Bromine in the nature
Where is it found?
Bromine is found in nature only
in combination with other elements. Most bromine is obtained almost directly from ordinary
sea water and brine mixtures left over from the production of potassium salts.
Abundance of Bromine
Abundance |
Parts per billion by weight |
Parts per billion by atoms |
| Universe |
7 |
0.1 |
| Sun |
no data |
no data |
| Meteorite (carbonaceous) |
1200 |
230 |
| Crustal rocks |
3000 |
780 |
| Sea water |
67300 |
5210 |
| Stream |
20 |
0.3 |
| Human |
2900 |
230 |
Where is Bromine used ?:
Summary:
Much of the bromine output in the U.S. was
used in the production of ethylene dibromide, a lead scavenger used in making gasoline
antiknock compounds. Lead in gasoline, however, has been drastically reduced, due to
environmental considerations. This will greatly affect future production of bromine.
Bromine is also used in making fumigants,
flameproofing agents, water purification compounds, dyes, medicinals, sanitizers,
inorganic bromides for photography, etc.
Organic bromides are also important.
More in detail:
The first known use of a bromine-containing
product was as a dye used to create the color "royal purple" in ancient Rome.
The bromine-containing chemical was produced naturally by marine mussels and extracted for
use as the purple dye. This was an arduous process and only the very wealthy could afford
clothes of this particular hue. Hence, the name "royal purple".
Today, bromine's use has expanded to a wide variety of products. Bromine is used in the
manufacture of fire retardants, water treatments, dyes, pharmaceuticals, pesticides, and
gasoline additives amongst other things. The manufacture of flame retardants is the most
important use of bromine. Bromine is one of the few chemical elements with fire-resistance
properties.
Bromine-containing chemicals are used in swimming pools and industrial cooling towers to
control algae, bacteria, and odors. Some bromine-containing pesticides are used in the
production or storage of food crops. Bromine also is used in the production of oil and gas
well completion drilling fluids. Thanks to bromine chemicals, we now have photographic
films and papers, dyes, inks, sedatives, analgesics, anesthetics and other drugs,
hydraulic fluids, refrigerating and dehumidifying agents, and hair-waving preparations.
Brominated Flame Retardants
Bromine is used as the building block for some of the most
effective flame-retarding agents available to the plastics industry today. They are used
to protect against the risk of accidental fire in such as computers, televisions, radios,
stereo systems, video players, and in products made of textiles and wood. Brominated flame
retardants also are used to improve the fire safety of foam padding used in upholstered
furniture, in the plastic coating on electrical wire, and even in carpeting.
Brominated flame retardants, as all flame retardants, act to decrease the risk of fire by
reducing the risk that an object will ignite. Many everyday objects are treated with
flame retardants so that common occurrences -- such as a TV or computer being left on all
night and overheating, an electrical short circuit occurring in an electronic device, or
cigarettes accidentally dropping on a sofa or curtain -- do not result in a fire.
In addition to reducing the likelihood that an item will ignite, flame retardants hinder
the spread of the fire, and provide valuable extra time in the early stages of a fire when
it is much easier to escape. A room fire can very quickly escalate to the point where
enough heat is generated that all combustible material in the room bursts into flames.
This situation is known as "flash-over" and can occur in a matter of minutes
from ignition. Flame retardants slow down the initial burn rate and thereby can help
increase the time to flash-over, giving the occupant more time to escape.
Fire Extinguishants
Where accidental fires have started, bromine-containing
compounds are frequently used as fire-extinguishing agents. Some are excellent vaporizing
liquid flame-extinguishing agents used in commercial fire and explosion suppression
systems. Some have been used in combination with an inert siliceous powder to extinguish
fires on liquid chlorosilanes. This system is superior to other extinguishers because it
does not evolve the toxic gases that are generated when water or conventional carbonate
extinguishers are used.
Pharmaceuticals
Many active ingredients in over-the-counter or prescription
drugs contain bromine. Many others rely on brominated intermediates during their
manufacture. One example is the general anesthetic, halothane, which contains a bromine
atom in its chemical structure.
- Naproxen, a new analgesic, utilizes a brominated
intermediate in its manufacture.
The antihistamine, bromopheniramine
maleate, and the cough medicine dextromethorphan hydrobromide, also utilize bromine in
their make-up.
1-Bromogalanthamine is being developed
for potential use in treating Alzheimer's Disease.
Bromhexine improved the performance of
amoxicillin in the treatment of pneumonia.
Bromocriptine is effective in the
treatment of cocaine addiction.
Many of the commonly used sedatives,
antihistamines and antitussives can be made at a lower cost thanks to bromine chemistry.
Some of the new anti-cancer drugs will be
made using bromine chemistry.
Biocides and Pesticides
A number of bromine-containing products are used as biocides
and pesticides. Brominated biocides are used in recreational
(swimming pools) and industrial water treatment to control algae and bacterial growth and
odor. The main bromine compounds used in biocide applications are sodium bromide and
bromochlorodimethylhydantoin.
Certain brominated chemicals are also very effective pesticides. Methyl bromide is a
highly effective soil fumigant and fumigant for stored grain and produce. Historically,
methyl bromide has been used to treat insect and nematode infestations in high value
crops, including strawberries, tomatoes, melons, and tobacco.
Solvents
Many solvent users are switching from chlorinated solvents to
brominated solvents because of
Brominated solvents are excellent
options for users who want to obtain optimal cleaning performance and low-to-no
flammability.
Oil field chemicals
The world's oilfields rely on bromine chemicals for completion
and work-over. These same chemicals provide drillers with high-performance fluids for
horizontal drilling and drilling in deep, high pressure fields.
Photographic chemicals
Bromine compounds have a number of applications in photography.
Several compounds are used to make the all-important light-sensitive component of a
photographic emulsion - without these bromine compounds your pictures will not capture the
light. Other bromine compounds are used as an ingredient in photo developing solutions -
without them your pictures wouldn't be developed.
Other Uses of Bromine Chemicals
Bromine compounds are being tested in new batteries for
electric vehicles designed to have zero emissions. This potential market for bromine
compounds may have a big positive impact on our environment.