General Information

Atomic symbol As
Atomic number 33
Atomic mass 74.92
Melting point 817.0o C
Boiling point 613.0o C
Number of protons/electrons 33
Number of neutrons 42
Classification Metalloid
Crystal Structure Rhombohedral
Density 5.72g/cm3
Colour Grey
Origin Mispickel, arsenopyrite, (FeSAs) is the most common mineral from
which, on heating, the arsenic sublimes leaving ferrous sulfide.
Common compounds AsH3; As2O5; As4O6; AsO; AsI5; AsI3; [AsI2]2; AsBr3; AsCl5;
AsCl3; AsF5; AsF3.
Isotopes (Natural / radioactive) 75As / 69As; 70As; 71As; 72As; 73As; 74As; 76As; 77As; 78As; 79As.
Origin of name Latin: arsenicum, Greek: arsenikon, yellow orpiment, identified
with arenikos, male, from the belief that metals were different
sexes; Arabic, Az-zernikh, the orpiment from Persian zerni-zar, gold
Properties Elemental arsenic occurs in two solid modifications: yellow, and gray
or metallic, with specific gravities of 1.97, and 5.73, respectively.
The element is a steel gray, very brittle, crystalline, semimetallic
solid; it tarnishes in air, and when heated is rapidly oxidized to
arsenous oxide with the odor of garlic. Arsenic and its compounds
are poisonous.
Uses Arsenic is used in bronzing, pyrotechny, and for hardening and
improving the sphericity of shot. The most important compounds
are white arsenic, the sulfide, Paris green, calcium arsenate, and
lead arsenate; the last three have been used as agricultural
insecticides and poisons. Marsh's test makes use of the formation
and ready decomposition of arsine. Arsenic is finding increasing
uses as a doping agent in solid-state devices such as transistors.
Gallium arsenide is used as a laser material to convert electricity
directly into coherent light.