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C4H8N8O8
Percent Composition by Number:
Type of Bonding:
Production: |
C4H8N8O8
Percent Composition by Number:
Carbon: 14.3%
Hydrogen: 28.6%
Nitrogen: 28.6%
Oxygen: 28.6%
Percent Composition by Mass:
Carbon:
16.2%
Hydrogen:
2.70%
Nitrogen:
37.8%
Oxygen: 43.2%
Type of Bonding:
HMX is held together by covalent bonds. Several small molecules are bonded
to the corners of a hexagonal shaped center.
Production:
HMX does not occur in nature and must be made in a very expensive and
difficult process. The process is outlined in the US Army's Military
Explosives manual as such: "To manufacture HMX, a solution of 785 parts
glacial acetic acid, 13 parts acetic anhydride, and 17 parts
paraformaldehyde is maintained at a temperature of 44oC ± 1oC.
All part measurements in this discussion are by weight. The solution is held
at that temperature throughout the subsequent steps of the process. Two more
solutions are prepared. One consists of 101 parts hexamine and 165 parts
acetic acid. The other is prepared by dissolving 840 parts ammonium nitrate
in 900 parts of 99 percent or stronger nitric acid. Over a 15 minute period
with constant stirring, the hexamine-acetic acid solution, 180 parts of the
nitric acid-ammonium nitrate solution, and 320 parts acetic anhydride are
added simultaneously, continuously, and equivalently. The mixture is aged
for 15 minutes. In the second stage of the reaction, 320 parts of acetic
anhydride and 271 parts of the nitric acid-ammonium nitrate solution are
added proportionately, then 160 parts of acetic anhydride are added in bulk.
The mixture is allowed to age for 60 minutes. Then 350 parts hot water are
added and the solution is refluxed for 30 minutes. After cooling to 20oC
by adding ice, the water insoluble precipitate is collected and washed with
three portions of cold water. The yield of 200 parts HMX is 95 percent of
the theoretical and the purity is higher than 90 percent."